Poly(methylhydrosiloxane)
Supplier: Thermo Scientific
L14561.0BEA
213
EUR
L14561.0B
L14561.30
L14561.18
Poly(methylhydrosiloxane)
Poly(methylhydrosiloxane)
Poly(methylhydrosiloxane) is used in the reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr. It is a safer alternative to triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. It is also used in greener amine synthesis by reductive amination as an alternative to borohydrides.
Formula:
(CH₃)₃SiO[(CH₃)HSiO]nSi(CH₃) Boiling Pt: ∼140 °C (0,003 hPa) Melting Pt: –55 °C Density: 1,006 Flash Pt: 204 °C (399 °F) |
MDL Number:
MFCD00084478 CAS Number: 63148-57-2 |
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