Poly(methylhydrosiloxane)

Supplier: Thermo Scientific

L14561.0BEA 213 EUR
L14561.0B L14561.30 L14561.18
Poly(methylhydrosiloxane)
Poly(methylhydrosiloxane)

Poly(methylhydrosiloxane) is used in the reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr. It is a safer alternative to triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. It is also used in greener amine synthesis by reductive amination as an alternative to borohydrides.

Formula: (CH₃)₃SiO[(CH₃)HSiO]nSi(CH₃)
Boiling Pt: ∼140 °C (0,003 hPa)
Melting Pt: –55 °C
Density: 1,006
Flash Pt: 204 °C (399 °F)
MDL Number: MFCD00084478
CAS Number: 63148-57-2

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